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Flexible electronic devices play a non-negligible role in health monitoring, sensing skin, implantable devices, etc.
Among them, hydrogels are considered as a an attractive candidate material
.
Recently, Professor Yuanjin Zhao from Southeast University published an article titled "Bio‐Inspired Stretchable, Adhesive, and Conductive Structural Color Film for Visually Flexible Electronics" in Advanced Functional Materials.
Mechanistically, a novel carbon nanotube-polydopamine (PDA) and elastic polyurethane (PU) polymer hybrid structural color film is proposed for visualizing flexible electronics
.
Graphical guide
Graphical guide1.
Construction and performance of hybrid membranes
Construction and performance of hybrid membranes
First, a colloidal crystal template was obtained from the self-assembly of silica nanoparticles by a vertical deposition method, and then a PU inverse opal-structured hydrogel film was prepared by replicating the template
.
Fig.
1 Structure and microstructure of the hybrid films
.
Owing to the ordered inverse opal nanostructure, the PU hydrogel films have vivid structural color, which is determined by the photonic band gap (PBG) property, in which light of the same frequency is forbidden to propagate and selectively reflection
.
Figure 2.
Conductivity and color-sensing properties of hybrid films
.
Taking advantage of the advantages of PDA, the hybrid membrane also has excellent adhesion and self-healing properties, which can promote the interaction between skin and membrane in practical applications
.
Fig.
3 Adhesion and self-healing properties of hybrid films
.
2.
Practical application
Practical application
By using the template forming method, the film can be easily designed in different patterns, such as fish, six-leaf flower and four-leaf clover
.
In this process, hybrid films with different structural colors are first produced
.
Based on the aforementioned self-healing properties, the fragments can be glued together to form a complete object
.
These complex patterned films make them functional materials in different fields
.
Figure 4 Patterned self-healing hybrid structural color film
.
ac) Schematic and optical images of color films of various patterned self-healing hybrid structures with a) fish, b) six-leaf flower, and c) four-leaf clover shapes
.
Considering its electrical conductivity, adhesion, self-healing, and structural color sensing capabilities, the composite film is expected to be used in flexible electronics
.
To illustrate this, joint motion was monitored by directly affixing the membranes to the fingers, wrist, and elbow, respectively
.
In the case of finger movement, when the bending angle gradually increases, the structural color of the film transitions from orange-red to green, and even if the finger moves continuously, it shows good stability and excellent optical sensing performance
.
At the same time, real-time resistance changes were recorded.
With the deformation of the finger, the resistance value of the film increased or decreased accordingly
.
The film exhibits color-changing ability and stable and sensitive conductivity in dynamic activities, and has potential applications in flexible human motion sensors for real-time color sensing and electrical signal monitoring
.
Figure 5.
Conductivity responses to various real-time human motions
.
ac) Photographs of polymer conductive hydrogel hybrid structural color films responding to bending motion of a) finger, b) wrist, and c) elbow, respectively
.
α, β, and γ denote the bending angles of the finger, wrist and elbow bending motions, respectively
.
df) Wavelength shift values of the films, corresponding to different bending angles of d) finger, e) wrist and f) elbow, respectively
.
gi) The relative resistance of the hybrid structural color film varies with different angles of g) finger, h) wrist and i) elbow
.
Highlights Summary
Highlights SummaryIn summary, inspired by natural organisms, the authors introduced CNTs-PDA fillers into PU inverse opal scaffolds to develop a new type of elastic polymer conductive hydrogel hybrid structural color film
.
The film has stable tensile properties and bright structural color
.
In addition, the presence of carbon nanotubes endows the film with good electrical conductivity, and utilizing the advantages of PDA, the film has excellent adhesion and self-healing properties
.
Due to the responsiveness of structural colors, the prepared films have the ability to change color and can be used as dual-signal flexible human motion sensors for real-time color sensing monitoring and electrical signal monitoring
.