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Chinese scholars have made progress in the selective CH functionalization of aromatic sites

 Last Update: 2021-09-03
 Source: Internet
 Author: User

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synthesis chemistry

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Aromatics and their derivatives are important synthetic raw materials in the fields of chemical medicine and functional materials

This research introduces azo as a guiding group, through the hydrogen bonding and conjugation effect of organic catalyst chiral phosphoric acid and azo to realize the activation of benzene ring and site-selective conversion.

Figure 1 Organo-catalyzed para-selective CH functionalization of aromatic hydrocarbons

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