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Chinese scholars have made progress in asymmetric free radical cross-coupling

 Last Update: 2022-08-11
 Source: Internet
 Author: User

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Figure (A) Chiral control mode of radical species; (B) Design of chiral ligands based on reaction mechanism; (C) Precise construction of chiral quaternary carbon molecular building blocks

Under the support of the National Natural Science Foundation of China (Grant .

Free radical reactions are widely used in synthetic chemistry, medicinal chemistry, materials chemistry and life scienc.

Xinyuan Liu's team developed the concept of "chiral anionic copper single-electron catalyst" in asymmetric radical chemistry, and realized the enantioselective control of alkyl radical species by using a variety of chiral regulation pathwa.

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