Whether in the industrial synthesis of ammonia or in the process of biological nitrogen fixation, the iron nitrogen species (Fe≡N) is regarded as a key intermediate for the reduction and conversion of nitrogen into ammonia
The study explained that iron-nitrogen species is a key intermediate in the process of industrial ammonia synthesis and biological nitrogen fixation from the molecular level, and will provide important design strategies and research methods for the development of new milder and more efficient green ammonia synthesis catalysts
Figure The structure of sulfur-bridged double iron nitride and the reaction of stepwise hydrogenation and high-efficiency reduction and release of ammonia
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